Research Highlights

In a recent Science paper, researchers led by JILA and NIST Fellow Jun Ye, along with collaborators JILA and NIST Fellow David Nesbitt, scientists from the University of Nevada, Reno, and Harvard University, observed novel ergodicity-breaking in C60, a highly symmetric molecule composed of 60 carbon atoms arranged on the vertices of a “soccer ball” pattern (with 20 hexagon faces and 12 pentagon faces). Their results revealed ergodicity breaking in the rotations of C60. Remarkably, they found that this ergodicity breaking occurs without symmetry breaking and can even turn on and off as the molecule spins faster and faster. Understanding ergodicity breaking can help scientists design better-optimized materials for energy and heat transfer. 

Many everyday systems exhibit “ergodicity” such as heat spreading across a frying pan and smoke filling a room. In other words, matter or energy spreads evenly over time to all system parts as energy conservation allows. On the other hand, understanding how systems can violate (or “break”) ergodicity, such as magnets or superconductors, helps scientists understand and engineer other exotic states of matter.

In a new ACS Nano paper, JILA and NIST Fellow David Nesbitt, along with former graduate student Jacob Pettine and other collaborators, developed a new method for measuring the dynamics of specific particles known as “hot carriers,” as a function of both time and energy, unveiling detailed information that can be used to improve collection efficiencies.

Metal ions can be found in almost every environment, including wastewater, chemical waste and electronic recycling waste. Properly recovering and recycling valuable metals from various sources is crucial for sustainable resource management and contributes to environmental cleanup. Because of the scarcity of some of these metals, such as rare earth elements or nickel, scientists are working to find ways to remove these ions from the waste and recycle the metals. One method used to remove these metals is to bind them to other molecules known as chelators or chelating agents. Chelators have multiple molecular groups that combine to form binding sites with a natural affinity for binding metal ions, making them a natural choice to extract metals from toxic waste. Ethylenediaminetetraacetic acid, or EDTA, is a chelator commonly used in metal removal and many other applications, including medicine. “EDTA is used to treat heavy-metal poisoning,” JILA graduate student Lane Terry explained. “So, if you have lead poisoning, you can take EDTA, which binds to the lead and then safely passes through your system. It's also used as a food preservative. So EDTA is everywhere. It's in one of my topical creams, etc.” EDTA is also commonly used in various laboratories, including many within JILA. 

To understand how EDTA binds to these metal ions and water molecules, Madison Foreman, a former JILA graduate student in the Weber group, now a postdoctoral researcher at the University of California, Berkeley, Terry, and their supervisor, JILA Fellow J. Mathias Weber, studied the geometry of the EDTA binding site using a unique method that helped to isolate the molecules and their bound ions, allowing for more in-depth analyses of the binding interactions. They published a series of three papers on this topic. In their first paper, published in the Journal of Physical Chemistry A, they found that the size of the metal ion changes where it sits in the EDTA binding site, which affects other binding interactions, especially with water. 

Some of the biggest questions about our universe may be solved by scientists using its tiniest particles. Since the 1960s, physicists have been looking at particle interactions to understand an observed imbalance of matter and antimatter in the universe. Much of the work has focused on interactions that violate charge and parity (CP) symmetry. This symmetry refers to a lack of change in our universe if all particles’ charges and orientations were inverted. “This charge and parity symmetry is the symmetry that high-energy physicists say needs to be violated to result in this imbalance between matter and antimatter,” explained JILA research associate Luke Caldwell. To try to find evidence of this violation of CP symmetry, JILA and NIST Fellows Jun Ye and Eric Cornell, and their teams, including Caldwell, collaborated to measure the electron electric dipole moment (eEDM), which is often used as a proxy measure for the CP symmetry violation. The eEDM is an asymmetric distortion of the electron’s charge distribution along the axis of its spin. To try to measure this distortion, the researchers used a complex setup of lasers and a novel ion trap. Their results, published in Science as the cover story and Physical Review A, leveraged a longer experiment time to improve the precision measurement by a factor of 2.4, setting new records. 

Quantum materials, a fascinating class of materials that harness the power of quantum mechanics, are revolutionizing modern science and technology. Quantum materials often possess exotic states of matter, such as superconductivity or magnetic ordering, that defy conventional understanding and can be manipulated for various technological applications. To further enhance and manipulate the intriguing characteristics of quantum materials, researchers leverage nanostructuring—the ability to precisely control the geometry on the atomic scale. Specifically, nanostructuring provides the ability to manipulate and fine-tune the electrical and thermal properties of quantum and other materials. This can result, for example, in designer structures that conduct current very well, but impede heat transport. A related critical challenge for a broad range of nanotechnologies is the need for more efficient cooling so that the nanodevices do not overheat during operation. To better understand heat transport at the nanoscale, JILA Fellows Margaret Murnane, Henry Kapteyn, and their research groups within the STROBE NSF Center, JILA, and the University of Colorado Boulder, created the first general analytical theory of nanoscale-confined heat transport, that can be used to engineer heat transport in 3D nanosystems—such as nanowires and nanomeshes—that are of great interest for next-generation energy-efficient devices. This discovery was published in NanoLetters. 

Two-dimensional materials, like graphene and 2D semiconductors, are an area of physics that has been growing tremendously in the last decade. According to JILA graduate student Ben Whetten, “That’s because they exhibit new spin and electronic physical phenomena and have much promise to build new miniaturized photonic or semiconductor nanoscale devices.” Researchers like Whetten, and his advisor, JILA Fellow, and University of Colorado Boulder professor Markus Raschke, develop methods to image these materials, giving a better understanding of their inner workings. In a new paper in NanoLetters, Raschke, and his team extended their ultrafast microscope to see nanometer-sized imperfection(s) within a 2D semiconductor sample that created some surprising nonlinear optical effects. 

The best clock in the world has no hands, no pendulum, no face or digital display. It is made of ultra-cold atoms trapped by light.  This atomic clock is so precise that, had it begun ticking when Earth formed billions of years ago, it would not yet have gained or lost a second. Nonetheless, this incredible clock, and all atomic clocks, operate with collections of independent atoms, and as a result, their precision is limited by the fundamental laws of quantum mechanics.  One way to get around this fundamental quantum imprecision is to entangle the atoms, or make them talk, in such a way that one cannot describe the individual atoms’ quantum states independently of one another. In this case it is possible to create the situation where the quantum noise of one atom in the clock can be partially canceled by the quantum noise of another atom such that the total noise is quieter than one would expect for independent atoms. One type of entangled state is called a “squeezed state”, which can be visualized as if one had shaped the quantum noise in a way that is narrower in one direction at the expense of making the fuzziness in the adjacent direction worse.  Squeezed states have been realized in several labs around the world at groundbreaking precision levels recorded by several physics institutes, including  at JILA in Boulder, Colorado.  However, squeezing is experimentally challenging to create and there is a need for a variety of “flavors” of squeezing for different types of quantum sensing tasks.

A new approach recently described in Physical Review Letters explores a new way to generate squeezing that is exponentially faster than previous experiments and generates a new flavor of entanglement:  two-mode squeezing—a type of entanglement that is thought to be used for improving the best atomic clocks and for sensing how gravity changes the flow of time. This promising new approach was developed by a collaboration of JILA and NIST Fellows Ana Maria Rey and James K. Thompson, and their team members, along with Bhuvanesh Sundar, a former postdoctoral researcher at JILA now at Rigetti Computing, and former JILA research associate Dr. Robert Lewis-Swan, now an Assistant Professor at the University of Oklahoma.

Although one might think it would be simple, the genetics of bacteria can be rather complicated. A bacterium’s genes use a set of regulatory proteins and other molecules to monitor and change genetic expressions within the organism. One such mechanism is the riboswitch, a small piece of RNA that can turn a gene “on” or “off.” In order to “flip” this genetic switch, a riboswitch must bind to a specific ion or molecule, called a ligand, at a special riboswitch site called the aptamer. The ligand either activates the riboswitch (allowing it to regulate gene expression) or inactivates it until the ligand unbinds and leaves the aptamer. Understanding the relationship between ligands and aptamers can have big implications for many fields, including healthcare.  “Understanding riboswitches and gene expression can help us develop better antimicrobial drugs,” explained JILA graduate student Andrea Marton Menendez. “The more we know about how to attack bacteria, the better, and if we can just target one small interaction that prevents or abets a gene from being translated or transcribed, we may have an easier way to treat bacterial infections.”  
To better understand the dynamics of aptamer and ligand binding, Marton Menendez, along with JILA and NIST Fellow David Nesbitt, looked at the lysine (an amino acid) riboswitch in Bacillus subtilis, a common type of bacterium present in environments ranging from cow stomachs to deep sea hydrothermal vents. With this model organism, the researchers studied how different secondary ligands, like, potassium, cesium, and sodium, affect riboswitch activation, or its physical folding. The results have been published in the Journal of Physical Chemistry B.

For a new study, a team of physicists recruited roughly 1,000 undergraduate students at CU Boulder to help answer one of the most enduring questions about the sun: How does the star’s outermost atmosphere, or “corona,” get so hot?

The research represents a nearly-unprecedented feat of data analysis: From 2020 to 2022, the small army of mostly first- and second-year students examined the physics of more than 600 real solar flares—gigantic eruptions of energy from the sun’s roiling corona. 

The researchers, partially lead by JILA fellow Heather Lewandowski, and including 995 undergraduate and graduate students, published their finding May 9 in The Astrophysical Journal. The results suggest that solar flares may not be responsible for superheating the sun’s corona, as a popular theory in astrophysics suggests. 
 

Dipolar gases have become an increasingly important topic in the field of quantum physics in recent years. These gases consist of atoms or molecules that possess a non-zero electric dipole moment, which gives rise to long-range dipole-dipole interactions between particles. These interactions can lead to a variety of interesting and exotic quantum phenomena that are not observed in conventional gases. 

For decades, black holes have fascinated scientists and nonscientists alike. Their ominous voids, like an open pair of jaws, has inspired a whole wave of science-fiction featuring the phenomenon. Physicists have also been similarly inspired, specifically to understand the dynamics of what is happening inside of the black hole, especially for objects thatmay fall in. The historical theories about black holes are closely linked to those within quantum physics and they suggest interesting phenomena. “The best models of black holes we have in general relativity, like the Kerr metric or the Reissner-Nordström metric, actually make some pretty crazy predictions,” explained JILA graduate student Tyler McMaken. “After you fall in, you eventually reach a spot, called the inner horizon, where we can enter into a wormhole, see a naked singularity [A region in space-time at which matter is infinitely dense], time-travel, and do a bunch of things that go against what we think should be physically possible.” To better understand the quantum mechanics of these black hole models, McMaken and JILA Fellow Andrew Hamilton and looked into the quantum effects that may be happening around and inside a black hole. From their research, they found that there was a divergence of energy into multiple levels at the inner horizon of the black hole, suggesting that quantum effects play a crucial role in how to model realistic black holes. “The exciting part of this research is the discovery that quantum effects save the day—as you approach the inner horizon, you're met with a wall of diverging energy from Hawking radiation, so that any weird, causality-violating parts of the spacetime are completely blocked off and replaced with a singularity,” McMaken added. This diverging energy split the radiation into multiple levels. “Without a full theory of quantum gravity, we won’t know exactly what happens at this singularity, but we do know that just like the Big Bang singularity, or the singularity we might find in simpler spherical black holes, it marks the end of spacetime as we know it as the curvature exceeds the Planck scale.” The results of the study have been submitted by McMaken and Hamilton for publication in the journal Physical Review D.

JILA researchers have upgraded a breathalyzer based on Nobel Prize-winning frequency-comb technology and combined it with machine learning to detect SARS-CoV-2 infection in 170 volunteer subjects with excellent accuracy. Their achievement represents the first real-world test of the technology’s capability to diagnose disease in exhaled human breath.

When a superconducting material is cooled down below a critical temperature, something seemingly magical happens: its electrical resistivity drops abruptly to zero! Initially, before 1911, this was thought to be impossible, given that electrons, which are the particles that carry electric current, typically scatter from impurities and imperfections of a crystal lattice used in conducting materials.  Moreover, because electrons are negatively charged particles, they typically repel each other. Yet, behind the “magic” of superconductors is the fact that two electrons, in a periodic crystalline array of atoms (a web of lasers), can attract positive charges in the lattice, whose subsequent deformation mediates an attractive interaction between the electrons. This attraction favors electrons with opposite momenta to bind together, forming ‘Cooper pairs’. These pairs can coalesce into a coherent macroscopic quantum state of matter, in which they remain paired while flowing through the crystal without any resistance. Beyond their immense practical applications, superconductors also offer a promising testbed to study the fundamental physics of matter held far away from equilibrium.

In a conventional superconductor (‘s-wave’ superconductor), the two electrons in a Cooper pair must have opposite spins. But there are unconventional superconductors with p-wave symmetry, in which electrons of the same spin pair up.  This pairing is penalized by an energy barrier and in order to overcome the barrier and pair up, electrons need to carry a non-zero angular momentum, which means that they need to spin around each other. The net angular momentum of the Cooper pairs can give rise to rich quantum behaviors and phases of matter that are intensively sought in real materials and cold atoms, but have, so far, remained elusive.  In particular, the dynamics of p-wave superconductors taken away from equilibrium is predicted to exhibit a variety of temporal behaviors, some of which possess interesting quantum dynamics. Observing these ‘dynamical phases’ in the lab would provide a window into the nature of non-equilibrium phases of matter and some of their properties, and potentially new p-wave superconductors. In cold gases, one of the biggest challenges that has prevented researchers from observing p-wave physics is three-body losses in energy that emerge when weak p-wave interactions are enhanced via external electromagnetic fields. However, to date, liquid 3He remains the only well-established laboratory example of a p-wave superconductor.

To overcome these challenges, JILA and NIST Fellow Ana Maria Rey collaborated with NIST (National Institute of Standards and Technology) Ion Storage Group leader John Bollinger, and researchers at the University of Innsbruck, Rutgers University and the University of Colorado Boulder, to design a trapped-ion simulator for 2D p-wave superconductors. Their work paves a way for clean observations of the predicted non-equilibrium dynamics in future experiments using the trapped-ion simulator, or Penning trap. The researchers published their findings in PRX Quantum.

Quantum gases of interacting molecules can exhibit unique dynamics. JILA and NIST Physicist Jun Ye has spent years of research to reveal, probe, and control these dynamics with potassium-rubidium molecules. In a new article published in Nature, Ye and his team of researchers describe having combined two threads of previous research—spin and motional dynamics—to reveal rich many-body and collisional physics that are controllable in the laboratory. 

Though microscopes have been in use for centuries, there is still much that we cannot see at the smallest length scales. Current microscopies range from the simple optical microscopes used in high school science classes, to x-ray microscopes that can image through visibly-opaque objects, to electron microscopes that use electrons instead of light to capture images of vaccines and viruses. However, there is a great need to see beyond the static structure of an object—to be able capture a nano- or biosystem functioning in real time, or to visualize the magnetic field on nanometer scales. A team of researchers from the STROBE Center have been working together to overcome these challenges. STROBE is an NSF Science and Technology Center led by JILA Fellow Margaret Murnane. The large and multidisciplinary collaboration included Chen-Ting Liao and the Kapteyn-Murnane group from JILA, the Miao and Osher groups from University of California Los Angeles, Ezio Iacocca from University of Colorado, Colorado Springs, David Shapiro and collaborators at Lawrence Berkley National Laboratory, and the Badding and Crespi groups from Pennsylvania State University. They developed and implemented a new method to use x-ray beams to capture the 3D magnetic texture in a material with very high 10-nanometer spatial resolution for the first time. They published their new technique and new scientific findings in Nature Nanotechnology.

When it comes to creating ever more intriguing quantum systems, a constant need is finding new ways to observe them in a wide range of physical scenarios.  JILA Fellow Cindy Regal and JILA and NIST Fellow Ana Maria Rey have teamed up with Oriol Romero-Isart, a professor at the University of Innsbruck and IQOQI (Institute for Quantum Optics and Quantum Information) to show that a trapped particle in the form of an atom readily reveals its full quantum state with quite simple ingredients, opening up opportunities for studies of the quantum state of ever larger particles.

There are many methods to determine what the limits are for certain processes. Many of these methods look to reach the upper and lower bounds to identify them for making accurate measurements and calculations. In the growing field of quantum sensing, these limits have yet to be found.  That may change, thanks to research done by JILA Fellow Graeme Smith and his research team, with JILA and NIST Fellow James Thompson In a new study published in Physical Review Applied, the JILA and NIST researchers collaborated with scientists at the quantum company Quantinuum (previously Honeywell Quantum Solutions) to try and identify the upper limits of quantum sensing.

At ultra-cold temperatures, quantum mechanics dictate how particles bump into each other. The collisions depend both on the quantum statistics of the colliding partners (their location within the medium) and on their collisional energy and angular momentum.  The angular momentum of the particles creates an energy barrier, a field of energy that prevents two molecules from interacting, and which can also affect particle dynamics in the quantum realm. The two main types of interactions at the quantum level are s-waves and p-waves. S-wave types of collisions happen naturally between fermions when they exist together in two different internal states and happen with zero angular momenta, which creates a low energy barrier. That means that atoms can collide “head-on.” S-wave collisions have been very well studied and characterized.  However, quantum statistics prevents identical fermions (those having the same internal state) to collide via s-wave interactions, instead forcing them to interact via the so-called “p-wave” channel. 

However, quantum statistics prevents identical fermions (having the same internal state) to collide via s-wave interactions, instead forcing them to interact via the so-called “p-wave” channel.  In contrast with s-wave interactions, p-wave interactions are penalized by the aforementioned energy barrier.In order to collide, particles need to carry a non-zero angular momentum in order to overcome that barrier—they need to spin around each other, like a pair of dancers. The net angular momentum of the partners can give rise to rich quantum behaviors and phases of matter that have been intensively sought in real materials and cold atoms, but which have not yet been found. Besides the energy barrier, the dynamics of three-body recombination, which involves interactions when three atoms are present rather than two, can make it complicated to study p-wave interactions in an isolated space. To overcome these problems, and to measure coherent p-wave interactions between two particles for the first time, JILA and NIST Fellow Ana Maria Rey and her group, together with JILA theorist Jose D’Incao, collaborated with the University of Toronto experimentalist team led by Joseph Thywissen. They devised a method to isolate pairs of atoms in an optical lattice, a web of laser light that helps isolate and control particle interactions, then gave the particles the necessary angular momentum, or twist, for the atoms to collide via p-wave using specific laser beam frequencies. This resulted in the first observation of p-wave interactions in an experiment. The researchers have published their findings in the journal Nature.

Sitting 150 million kilometers away from the Earth, the Sun produces puzzling phenomena, like solar flares, that physicists are working to understand. One of these puzzles involves the Sun's tachocline, a belt of heat transition. “A tachocline is when the radiative interior of a star rotates like a solid ball, but the convection zone [an unstable outer heat layer in a star] rotates differently,” explained former JILA graduate student Loren Matilsky. “For geometric reference in the Sun, the outer 30% by radius is the convection zone, and the inner 70% by radius is the radiative interior.” Before leaving JILA to become a postdoctoral researcher at the University of California Santa Cruz, Matilsky collaborated with JILA Fellow Juri Toomre and his group at JILA to study the Sun's tachocline using computer simulations. In a new paper published in The Astrophysical Journal Letters, Matilsky and Toomre developed a new type of simulation, one where the tachocline is self-consistent and not artificially enforced, meaning that it arises on its own. According to Matilsky: “As far as we know, it's the first time this type of self-consistent tachocline behavior has been published for a fully nonlinear fluid dynamical global simulation.”

Atomic clocks are crucial for everyday living as they help our telecommunications, electrical power grids, GPS systems, transportation, and other processes around the world keep precise time. Some of these clocks use lasers and special resonator cavities to measure time intervals. They are some of the most accurate clocks in the world and the most fragile. The cesium atomic clocks play a consequential role, as a specific atomic transition induced in the atomic cesium is used to define the unit of time: the SI second.  The National Institute of Standards and Technology (NIST) laboratories in Boulder, Colorado have housed atomic clocks—including the cesium atomic clock NIST-F1 which serves as the United States' primary time and frequency standard—for decades, as researchers continue to improve the clocks' accuracies through cutting-edge research. For the NIST-F1 cesium clock specifically, this process has included rebuilding parts of the clock.